Barium & Chemicals, Inc.

Safety Data Sheet
Revision: 0
Revision Date: 5/6/2015

 


1.) Identification
 
        Product Name: Lithium Fluoride
        Product Number: LI1210
        Product Formula:
 
        Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

        Emergency Phone: Chemtrec 800-424-9300
        International: 703-527-3887

2.) HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Target Organ effect, Toxic by ingestion, Irritant
Target Organs
Central nervous system, Kidney, Cardiovascular system, Thyroid
GHS Classifications
Acute toxicity, Oral (3)
Skin irritation (2)
Eye Irritation (2A)
Specific target organ toxicity - single exposure (3)
GHS Label Elements, Including Precautionary Statements
Pictogram
Signal Word     Danger
Hazard Statement(s)
H301 Toxic if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
 
Precautionary Statement(s)
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
 
HMIS Classification
Health Hazard 2
Flammability 0
Physical Hazards 0
*
 
NFPA Rating
Health Hazard 2
Fire 0
Reactivity Hazard 0
 
Potential Health Effects
Inhalation May be harmful if inhaled. Causes respiratory tract irritation
Skin My be harmful if absorbed through skin Causes skin irritation
Eyes Causes eye irritation
Ingestion Toxic if swallowed

3.) INFORMATION ON INGREDIENTS
 
  EINECS PERCENT CAS NO:
232-152-0 100% 7789-24-4
  EINECS PERCENT CAS NO:

4.) FIRST AID MEASURES
 
Inhalation
If breathed in, move person into fresh ari. If not breathing give artificial respiration. Consult a physician.
Skin Contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
Eye Contact
Rinse throroughly with plenty of water for at least 15 minutes and consult a physcian
Ingestion Contact
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5.) FIRE FIGHTING MEASURES
 
Extinguishing Media
Not flammable or combustible,
Special Fire Fighting Procedures
Fire and Explosion Hazzards
Hazardous Combustion Products
Hazardous decomposition products formed under fire conditions - Hydrogen fluoride, Lithium oxides
Protective Measure in Fire
Wear self contained breathing apparatus for fire fighting if necessary

6.) ACCIDENTAL RELEASE MEASURES
 
Personal Precaution in Spill
Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breating dust.
Environment
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Spill Clean Up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Do not flush with water. Keep in suitable, closed containers for disposal.

7.) HANDLING AND STORAGE
 
Usage Precautions
Usage Descriptions
Storage Precautions
Keep container tightly closed in a dry and well-ventilated place. Never allow product to get in contact with water during storage. Do not store near acids.
Handling Precautions
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.

8.) EXPOSURE CONTORLS AND PERSONAL PROTECTION
 
Protective Equipment
Use PPE as indicated by risk assessment
Process Conditions
Respirators
If air-purifying respirators are appropriate use a full-face particle respirator type N100(US) or type P3(EN 143) respirator cartridges as a backup to engineering controls.
Protective Gloves
Handle with gloves. Use poper glove removal technique(without touching the glove's outer surface) to avoid skin contact with this product. Wash and dry hands
Eye Protection
Face shield and safety glasses NIOSH (US) or EN166 (EU) approved
Other Protection
Based on the concentration and amount of the dangerous substance at the specific workplace a complete chemical suit may be appropriate.
Hygienic Work Practices
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product

9.) PHYSICAL AND CHEMICAL PROPERTIES
 
a) Appearance (physical state, color, etc.)
Powder
b) Odor
no data available
c) Odor threshold
no data available
d) pH
7.0 - 8.5
e) Melting Point/freezing point
845 deg C
f) Initial boiling Point and boiling range
no data available
g) Flash Point
not applicable
h) Evaporation rate
no data available
i) Flammability (solid,gas)
no data available
j) Upper/lower flammability or explosive limits
no data available
k) Vapor pressure
no data available
l) Vapor density
no data available
m) Relative density
2.64 g/ml @ 25C (77F)
n) Solubility(ies)
ca 0.3g/l no data available
o) Partition coefficient: n-octanol/water
No data available
p) Auto-ignition temperature
No data available
q) Decomposition temperature
no data available
r) Viscosity
No data available
s) Specific Gravity
No data available

10.) STABILITY AND REACTIVITY
 
Stability
Stable under recommended storage conditions
Hazardous Decomp Products
Under fire, hazardous decomposition products formed. Hydrogen fluoride, Lithium oxides. Reacts with water to form Hydrogen fluoride
Conditions to Avoid
Avoid moisture

11.) TOXICOLOGICAL INFORMATION
 
Toxic Dose LD 50
ORAL RAT 143 mg/kg
Toxicological Info
Not available
Inhalation
not avaiable
Skin
no data available
Eyes
no data available
Medical Symptoms
no data available

12.) ECOLOGICAL INFORMATION
 
Toxicity
No data available
Distribution
No data available
Chemical Fate
No data available

13.) DISPOSAL CONSIDERATIONS
 
Disposal Methods
dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber
General Cleaning
offer surplus and non-recycable solutions to a licensed disposal company

14.) TRANSPORTATION INFORMATION
 
DOT - GROUND TRANSPORTATION
Proper Shipping Name
Toxic Solid inorganic, NOS (Lithium Fluoride)
Hazzard Class
6.1
UN Number
UN3288
Packing Group
III
IATA/IMDG REGULATIONS
Proper Shipping Name
Toxic Solid inorganic, NOS (Lithium Fluoride)
Hazzard Class
6.1
UN Number
UN3288
Packing Group
III
IMDG EMS
F-A, S-A
Shipping Options for this product include
UPS    FedEx    Plane    Truck    Boat    Rail

Transportation Notes NMFC 43940-2 - CL 85 HST: 2826.19.9000


15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient CASNO TSCA EINECS China Japan Austrialia
Lithium Fluoride 7789-24-4 Yes Yes No No No

Chemical Inventory Status Part 2
Ingredient CASNO Korea DSL NDSL Phil.
Lithium Fluoride 7789-24-4 No No No No

Federal, State, International Regulations- Part 1
Ingredient CASNO SARA 302
    RQ TPQ LIST
Lithium Fluoride 7789-24-4 No No No
SARA 313

Federal, State, International Regulations- Part 2
Ingredient CASNO RCRA 261.33 TSCA 8(d) CERCLA
Lithium Fluoride 7789-24-4 No Yes No

Additional Items
Chemical Weapons Convention Acute TSCA 12(b) CDTA SARA 311/312 Reactivity Chronic
No No No No No No No
Fire Pressure Austrialian HazChem Code Poison Schedule WHMIS
No No No No No

16.) MISC. INFORMATION
 
Information Sources
Revision Comments
Created March 2014. Updated 2-19-2015
Other Information

17.) DISCLAIMER
 
Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this SDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this SDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except that it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.