Barium & Chemicals, Inc.

Safety Data Sheet
Revision: 1
Revision Date: 5/6/2015

 


1.) Identification
 
        Product Name: Copper (II) Carbonate, basic
        Product Number: CU1100
        Product Formula: Cu2CH2O5*H2O
 
        Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

        Emergency Phone: Chemtrec 800-424-9300
        International: 703-527-3887

2.) HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Acute Toxicity, Oral, skin irritation, eye irritation, specific target organ toxicity.
Target Organs
respiratory system
GHS Classifications
Acute toxicity, Oral (Category 4)
Skin irritation (Category 2)
Eye irritation (Category 2A)
Specific target organ toxicity - single exposure (Category 3)
GHS Label Elements, Including Precautionary Statements
Pictogram
Signal Word     Warning
Hazard Statement(s)
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye damage
H335 May cause respiratory irritation
 
Precautionary Statement(s)
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P305 + P351 + P338 IF IN EYES: Rinse cautiously wiht water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
 
HMIS Classification
Health Hazard 3
Flammability 0
Physical Hazards 0
 
NFPA Rating
Health Hazard 3
Fire 0
Reactivity Hazard 0
 
Potential Health Effects
Inhalation Causes respiratory tract irritation. May be harmful if inhaled
Skin Causes skin irritation. May be harmful if absorbed through skin.
Eyes Causes eye irritation.
Ingestion May cause gastrointestinal irritation with nausea, vomiting and diarrhea. may be harmful if swallowed.

3.) INFORMATION ON INGREDIENTS
 
  EINECS PERCENT CAS NO:
235-113-6 90-100 12069-69-1
  EINECS PERCENT CAS NO:

4.) FIRST AID MEASURES
 
Inhalation
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth to mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Skin Contact
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Eye Contact
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Ingestion Contact
If swallowed, get medical aid immediately. Only induce vomiting if directed to do so by medical personnel. never give anything by mouth to an unconscious person.
Note to Physician:
Treat symptomatically and supportively.

5.) FIRE FIGHTING MEASURES
 
Extinguishing Media
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Special Fire Fighting Procedures
Do not release runoff from fire control methods to sewers or waterways.
Fire and Explosion Hazzards
Non-Flammable
Hazardous Combustion Products
Irritating and toxic fumes and gases.
Protective Measure in Fire
Because fire may produce toxic thermal decomposition products, wear a self-contaminated breathing apparatus (SCBA) with full face-piece operated in pressure-demand or positive-pressure mode.

6.) ACCIDENTAL RELEASE MEASURES
 
Personal Precaution in Spill
Environment
Do not release into waterways or sewers.
Spill Clean Up
Small spills: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately. Large Spills: Dike far ahead of spill for later disposal.

7.) HANDLING AND STORAGE
 
Usage Precautions
Usage Descriptions
Storage Precautions
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling Precautions
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. use with adequate ventilation. Avoid contact with eyes, skin, and clothing. keep container tightly closed. Avoid ingestion and inhalation.

8.) EXPOSURE CONTORLS AND PERSONAL PROTECTION
 
Protective Equipment
Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OHSA eye-and face-protection regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses.
Process Conditions
Respirators
Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-approved respirator. For cleaning spills, reactor vessels, or storage tanks, wear an SCBA.
Protective Gloves
Wear chemically protective gloves.
Eye Protection
Wear protective eyeglasses or chemical safety goggles, per OHSA eye-and face-protection regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses.
Other Protection
Hygienic Work Practices
Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area. Separate contaminated work clothes from street clothes. Launder before use. Remove this material from shoes and clean PPE. Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics.

9.) PHYSICAL AND CHEMICAL PROPERTIES
 
a) Appearance (physical state, color, etc.)
Green to blue green to blue
b) Odor
No data available
c) Odor threshold
No data available
d) pH
No data available
e) Melting Point/freezing point
392 F
f) Initial boiling Point and boiling range
464 F
g) Flash Point
Not applicable
h) Evaporation rate
No data available
i) Flammability (solid,gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure
No data available
l) Vapor density
No data available
m) Relative density
4.000 g / cm 3
n) Solubility(ies)
insoluble in water No data available
o) Partition coefficient: n-octanol/water
No data available
p) Auto-ignition temperature
No data available
q) Decomposition temperature
No data available
r) Viscosity
No data available
s) Specific Gravity
No data available

10.) STABILITY AND REACTIVITY
 
Stability
Copper (II) Carbonate, basic is stable at room temperature in closed container under normal storage and handling conditions.
Hazardous Decomp Products
May include copper and carbon oxides.
Conditions to Avoid
incompatible materials, dust generation, excess heat, strong oxidants.

11.) TOXICOLOGICAL INFORMATION
 
Toxic Dose LD 50
Oral - rat - 1350 mg/kg Dermal - rabbit - > mg/kg
Toxicological Info
Inhalation
Skin
Eyes
Medical Symptoms

12.) ECOLOGICAL INFORMATION
 
Toxicity
No data available
Distribution
No data available
Chemical Fate
No data available

13.) DISPOSAL CONSIDERATIONS
 
Disposal Methods
Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and local regulations.
General Cleaning

14.) TRANSPORTATION INFORMATION
 
DOT - GROUND TRANSPORTATION
Proper Shipping Name

Hazzard Class

UN Number

Packing Group

IATA/IMDG REGULATIONS
Proper Shipping Name

Hazzard Class

UN Number

Packing Group

IMDG EMS

Shipping Options for this product include
UPS    FedEx    Plane    Truck    Boat    Rail

Transportation Notes US DOT (49 CFR 172.101)


15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient CASNO TSCA EINECS China Japan Austrialia
Copper (II) Carbonate, basic 12069-69-1 No No No No No

Chemical Inventory Status Part 2
Ingredient CASNO Korea DSL NDSL Phil.
Copper (II) Carbonate, basic 12069-69-1 No No No No

Federal, State, International Regulations- Part 1
Ingredient CASNO SARA 302
    RQ TPQ LIST
Copper (II) Carbonate, basic 12069-69-1 No No No
SARA 313

Federal, State, International Regulations- Part 2
Ingredient CASNO RCRA 261.33 TSCA 8(d) CERCLA
Copper (II) Carbonate, basic 12069-69-1 No No No

Additional Items
Chemical Weapons Convention Acute TSCA 12(b) CDTA SARA 311/312 Reactivity Chronic
No No No No No No No
Fire Pressure Austrialian HazChem Code Poison Schedule WHMIS
No No No No No

16.) MISC. INFORMATION
 
Information Sources
Revision Comments
Updated for GHS Standards 2-20-15
Other Information

17.) DISCLAIMER
 
Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this SDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this SDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except that it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.