Barium & Chemicals, Inc.

Safety Data Sheet
Revision: 0
Revision Date: 5/6/2015

 


1.) Identification
 
        Product Name: Lead Chromate
        Product Number: LE1180
        Product Formula: CrO4Pb
 
        Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

        Emergency Phone: Chemtrec 800-424-9300
        International: 703-527-3887

2.) HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Carcinogen
Target Organs
Teratogen: lungs, blood, kidney, nerves. Femail reproductive system. Male reproductive system.
GHS Classifications
Carcinogenicity (Category 1A)
Reproductive toxicity (Category 1A)
Specific target organ toxicity-repeated exposure (Category 2)
Acute aquatic toxicity (Category 1)
Chronic Aquatic toxicity (Category 2)
GHS Label Elements, Including Precautionary Statements
Pictogram
Signal Word     Danger
Hazard Statement(s)
H350 May Cause Cancer
H360 May damage fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H411 Toxic to aquatic life with long lasting results
 
Precautionary Statement(s)
P201 Obtain special instructions before use
P202 De not handle until all safety precautions have been read and understood
P260 Do not breathe dust/fume/gas/misyt/vapours/spray
P273 Avoid release to the environment
P281 Use personal protective equipment as required
P308/P313 If exposed or concerned Get medical advice/attention
 
HMIS Classification
Health Hazard 0
Flammability 0
Physical Hazards 3
 
NFPA Rating
Health Hazard 0
Fire 0
Reactivity Hazard 3
 
Potential Health Effects
Inhalation May be harmful if inhaled. May cause respiratory irritation
Skin May be harmful if absorbed through skin. May cause skin irritation
Eyes May cause eye irritation
Ingestion May be harmful if swallowed

3.) INFORMATION ON INGREDIENTS
 
  EINECS PERCENT CAS NO:
231-846-00 100% 7758-97-6
  EINECS PERCENT CAS NO:

4.) FIRST AID MEASURES
 
Inhalation
If breathed in, move person to fresh air. If not breathing, give artificial respiration. Consult a physician
Skin Contact
Wash off with soap and plenty of water. Consult a physician
Eye Contact
Flush eyes with water for at least 15 minutes and consult a physician
Ingestion Contact
Rinse mouth with water. Never give anything by mouth to an unconscious person. Consult a physician

5.) FIRE FIGHTING MEASURES
 
Extinguishing Media
Not flammable or combustible
Special Fire Fighting Procedures
Wear self contained breathing apparatus for fire fighting if necessary
Fire and Explosion Hazzards
product itself does not burn
Hazardous Combustion Products
Lead oxides and Chromium oxides may form under fire conditions
Protective Measure in Fire

6.) ACCIDENTAL RELEASE MEASURES
 
Personal Precaution in Spill
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas Avoid breathing dust.
Environment
Discharge to environment must be avoided.
Spill Clean Up
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

7.) HANDLING AND STORAGE
 
Usage Precautions
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.
Usage Descriptions
Wear proper protective equipment and avoid dust formation.
Storage Precautions
Keep container tightly closed in a dry and ewell ventilated place
Handling Precautions
Keep material dry

8.) EXPOSURE CONTORLS AND PERSONAL PROTECTION
 
Protective Equipment
Use local ventilation if dusting is a problem, to maintain air levels below the recommended exposure limit.
Process Conditions
Respirators
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US ) or Type P3(EN 143) respirator cartridges as backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN(EU)
Protective Gloves
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact. Dispose of contaminated gloves after use in appropriate contaners. Wash and dry hands
Eye Protection
Safety glasses with side-shields conforming to EN 166(EU). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN166 (EU).
Other Protection
Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Hygienic Work Practices
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of the workday

9.) PHYSICAL AND CHEMICAL PROPERTIES
 
a) Appearance (physical state, color, etc.)
Dark yellow Powder
b) Odor
No data Available
c) Odor threshold
No data available
d) pH
No data available
e) Melting Point/freezing point
No data available
f) Initial boiling Point and boiling range
No data Available
g) Flash Point
No Data Available
h) Evaporation rate
No data available
i) Flammability (solid,gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure
No data available
l) Vapor density
No data available
m) Relative density
No data available
n) Solubility(ies)
No data Available No data available
o) Partition coefficient: n-octanol/water
No data available
p) Auto-ignition temperature
No data available
q) Decomposition temperature
No data Available
r) Viscosity
No data available
s) Specific Gravity
No data available

10.) STABILITY AND REACTIVITY
 
Stability
Stable under recommended storage conditions
Hazardous Decomp Products
No data available
Conditions to Avoid
Organic materials, powdered metals

11.) TOXICOLOGICAL INFORMATION
 
Toxic Dose LD 50
<12,000 mg/kg
Toxicological Info
May cause damage to organs through prolonged or repeated exposure
Inhalation
No data available
Skin
No data Available
Eyes
No data Available
Medical Symptoms
Poisoning may affect the blood, central nervous system, liver, and kidneys.

12.) ECOLOGICAL INFORMATION
 
Toxicity
No data available
Distribution
No data available
Chemical Fate
No data available

13.) DISPOSAL CONSIDERATIONS
 
Disposal Methods
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator with an afterburner and scrubber.
General Cleaning
Wear protective equipment as noted

14.) TRANSPORTATION INFORMATION
 
DOT - GROUND TRANSPORTATION
Proper Shipping Name
Lead Chromate
Hazzard Class
9
UN Number
3077
Packing Group
III
IATA/IMDG REGULATIONS
Proper Shipping Name
Lead Chromate
Hazzard Class
9
UN Number
3077
Packing Group
III
IMDG EMS
F-A, S-F
Shipping Options for this product include
UPS    FedEx    Plane    Truck    Boat    Rail

Transportation Notes NMFC 43940-2 - CL 85 HST# 2841.90.45.00 UPS GROUND AND FEDEX GROUND (MAX PACKAGE WEIGHT 70 LBS)


15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient CASNO TSCA EINECS China Japan Austrialia
Lead Chromate 7758-97-6 Yes Yes Yes Yes Yes

Chemical Inventory Status Part 2
Ingredient CASNO Korea DSL NDSL Phil.
Lead Chromate 7758-97-6 No No No No

Federal, State, International Regulations- Part 1
Ingredient CASNO SARA 302
    RQ TPQ LIST
Lead Chromate 7758-97-6 No No No
SARA 313
Chronic Health Hazard

Federal, State, International Regulations- Part 2
Ingredient CASNO RCRA 261.33 TSCA 8(d) CERCLA
Lead Chromate 7758-97-6 No No No

Additional Items
Chemical Weapons Convention Acute TSCA 12(b) CDTA SARA 311/312 Reactivity Chronic
No No No No No No No
Fire Pressure Austrialian HazChem Code Poison Schedule WHMIS
No No No No No

16.) MISC. INFORMATION
 
Information Sources
Revision Comments
Revised November 2012 for GHS Standards. Updated 2-19-15 Revised February 2014 to align with internal document control
Other Information
Lead Chromate is included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/206 (REACH) Index NO 082-004-00-2

17.) DISCLAIMER
 
Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this SDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this SDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate precautionaly handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except htat it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, wiht respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.