Barium & Chemicals, Inc.

Safety Data Sheet
Revision: 5
Revision Date: 8/17/2016

 


1.) Identification
 
        Product Name: Barium Hydroxide Anhydrous
        Product Number: BA1250
        Product Formula: Ba(OH)2
 
        Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

        Emergency Phone: Chemtrec 800-424-9300
        International: 703-527-3887

2.) HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Target Organ Effect, Toxic by inhalation, Toxic by ingestion, Corrosive
Target Organs
Heart, Nerves, Kidney, Gastrointestinal tract, Bone marrow, Spleen, Liver
GHS Classifications
Acute toxicity, Oral (Category 4)
Skin corrosion (Category 1A)
Serious eye damage (Category 1)
GHS Label Elements, Including Precautionary Statements
Pictogram
Signal Word     Danger
Hazard Statement(s)
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes severe eye damage
 
Precautionary Statement(s)
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or Hair): Remove / Take off immediately all contaminated clothing. Rinse skin wiht water / shower
P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediatley call a POISON CENTER or doctor / physician
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor / physician.
 
HMIS Classification
Health Hazard 3
Flammability 0
Physical Hazards 0
Chronic Health Hazard *
 
NFPA Rating
Health Hazard 3
Fire 0
Reactivity Hazard 0
 
Potential Health Effects
Inhalation Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract.
Skin May be harmful if absorbed through skin. Causes skin burns.
Eyes Causes severe eye burns.
Ingestion Toxic if swallowed.

3.) INFORMATION ON INGREDIENTS
 
  EINECS PERCENT CAS NO:
241-234-5 100 17194-00-2
  EINECS PERCENT CAS NO:

4.) FIRST AID MEASURES
 
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Skin Contact
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse.
Eye Contact
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Ingestion Contact
If swallowed, give large quantities of water to drink and get medical attention immediately.DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious person.
Note to Physician
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.

5.) FIRE FIGHTING MEASURES
 
Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide
Special Fire Fighting Procedures
Not considered to be a fire hazard. Use fire fighting measures that suite the surrounding fire..
Fire and Explosion Hazzards
Not considered to be an explosion hazard.
Hazardous Combustion Products
No information found.
Protective Measure in Fire
Wear Self-contained respirator and fully protective impervious suit.

6.) ACCIDENTAL RELEASE MEASURES
 
Personal Precaution in Spill
Wear Self-contained respirator and fully protective impervious suit.
Environment
Prevent product from entering drains.
Spill Clean Up
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the PPE section.. Avoid generating dusty conditions. Provide ventilation.

7.) HANDLING AND STORAGE
 
Usage Precautions
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not breathe dust. Use only with adequate ventilation.
Usage Descriptions
Storage Precautions
Keep container closed when not in use. Store in a cool, dry, well ventilated area away from incompatible substances. Keep away from strong acids. Corrosives area.
Handling Precautions
Avoid formation of dust and aerosols. Keep the container tightly closed when not in use. Provide appropriate exhaust ventilation at places where dust is formed. Store in a cool, dry place.

8.) EXPOSURE CONTORLS AND PERSONAL PROTECTION
 
Protective Equipment
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Process Conditions
For soluble Barium compounds: OHSA Permissible Exposure Limit (PEL): 0.5 mg (Ba)/m3 ACGIH Threshold limit value (TLV)): 0.5 mg (Ba)/m3 A4 - no classified as a human carcinogen
Respirators
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN143) respirator cartridges as backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under OSHA 29 CFR 1910.134 and ANSI Z88.2 or European Standard EN 149.
Protective Gloves
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the Standard EN 374 derived from it. Handle with impervious protective gloves.
Eye Protection
Use chemical safety goggles and / or full face shield when dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work areas.
Other Protection
Wear appropriate protective clothing to minimize contact with skin. Always wear long pants, lonsleeved shirt.
Hygienic Work Practices
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of the workday.

9.) PHYSICAL AND CHEMICAL PROPERTIES
 
a) Appearance (physical state, color, etc.)
Colorless or white Crystalline solid.
b) Odor
Odorless
c) Odor threshold
No data available
d) pH
12.5 @ 50g/l @ 20C (68F)
e) Melting Point/freezing point
>300 C (>572 F) -lit.
f) Initial boiling Point and boiling range
not determined
g) Flash Point
not applicable
h) Evaporation rate
No data available
i) Flammability (solid,gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure
No data available
l) Vapor density
No data available
m) Relative density
2.2 g/ml @ 25 C (77F)
n) Solubility(ies)
Moderately in water (5.6 g/100ml) 5.6g / 100 g H2O @ 15 C(59 f)
o) Partition coefficient: n-octanol/water
No data available
p) Auto-ignition temperature
No data available
q) Decomposition temperature
Not determined
r) Viscosity
No data available
s) Specific Gravity
No data available

10.) STABILITY AND REACTIVITY
 
Stability
Stable under recommended comditions
Hazardous Decomp Products
Reacts with acids with toxic metal oxide fume production
Conditions to Avoid
Dust generation, excess heat, strong oxidizing agents.

11.) TOXICOLOGICAL INFORMATION
 
Toxic Dose LD 50
LD 50 Oral - rat 308 mg/kg
Toxicological Info
Acuet and chronic toxicity of this substance is not fully known.
Inhalation
Harmful to mucous membranes if inhaled.
Skin
Irritant to skin
Eyes
Irritating effect to eyes
Medical Symptoms
Symptoms of acute exposure include burns, nausea, diarrhea and vomiting. Edema of the larynx, spasm, laryngitis, SOB, Headache and edema of the bronchi could be present

12.) ECOLOGICAL INFORMATION
 
Toxicity
No information found
Distribution
No information found
Chemical Fate
This material may bioaccumulate. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

13.) DISPOSAL CONSIDERATIONS
 
Disposal Methods
Observe all federal, state and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material in the event of a large spill. Dissolve or mix the material with water, or if necessary with cleansinig agents. Dispose of as unused product.
General Cleaning
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.

14.) TRANSPORTATION INFORMATION
 
DOT - GROUND TRANSPORTATION
Proper Shipping Name
CORROSIVE SOLID TOXIC, NOS (BARIUM HYDROXIDE ANHYDROUS)
Hazzard Class
8(6.1)
UN Number
UN2923
Packing Group
III
IATA/IMDG REGULATIONS
Proper Shipping Name
CORROSIVE SOLID TOXIC, NOS (BARIUM HYDROXIDE ANHYDROUS)
Hazzard Class
8(6.1)
UN Number
UN2923
Packing Group
III
IMDG EMS
F-A,S-A
Shipping Options for this product include
UPS    FedEx    Plane    Truck    Boat    Rail

Transportation Notes NMFC 44155-8 - CL 77.5 HST#2816.40.20.00


15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient CASNO TSCA EINECS China Japan Austrialia
Barium Hydroxide Anhydrous 17194-00-2 Yes Yes No Yes Yes

Chemical Inventory Status Part 2
Ingredient CASNO Korea DSL NDSL Phil.
Barium Hydroxide Anhydrous 17194-00-2 Yes Yes No Yes

Federal, State, International Regulations- Part 1
Ingredient CASNO SARA 302
    RQ TPQ LIST
Barium Hydroxide Anhydrous 17194-00-2 No No No
SARA 313
Barium Compounds, NOS

Federal, State, International Regulations- Part 2
Ingredient CASNO RCRA 261.33 TSCA 8(d) CERCLA
Barium Hydroxide Anhydrous 17194-00-2 No No No

Additional Items
Chemical Weapons Convention Acute TSCA 12(b) CDTA SARA 311/312 Reactivity Chronic
No Yes No No Yes No No
Fire Pressure Austrialian HazChem Code Poison Schedule WHMIS
No No No No No

16.) MISC. INFORMATION
 
Information Sources
Revision Comments
Revised UN and hazard Code July 2013 . Updated 2-20-15 GHS Standards Revised February 2014 to align with internal document control Updated 8-17-2016
Other Information

17.) DISCLAIMER
 
Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this SDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this SDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except that it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.