Barium & Chemicals, Inc.

Safety Data Sheet
Revision: 5
Revision Date: 5/6/2015

 


1.) Identification
 
        Product Name: Calcium Resinate I (Fused)
        Product Number: CA1530
        Product Formula: Ca(C20H29O2)2
 
        Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

        Emergency Phone: Chemtrec 800-424-9300
        International: 703-527-3887

2.) HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
May cause skin irritation and/or dermatitis.
Target Organs
GHS Classifications
Irritating to Eyes, rinse with water
Irritating to Skin, rinse with soap and water
Acute inhalation hazard, remove to fresh air
Avoid ignition sources, may ignite when exposed to air
GHS Label Elements, Including Precautionary Statements
Pictogram
Signal Word     Danger
Hazard Statement(s)
H 228 / H252 flammable solid, Self-heating in large quantities, may catch fire
H302 / H312 / H315 Harmful if swallowed, in contact with skin or eyes
 
Precautionary Statement(s)
P210 Keep away from heat/sparks/open flames/hot surfaces, no smoking
P280 Wear Protective gloves/protective clothing / eye protection / face protection
 
HMIS Classification
Health Hazard 1
Flammability 3
Physical Hazards 1
 
NFPA Rating
Health Hazard 1
Fire 1
Reactivity Hazard 0
 
Potential Health Effects
Inhalation Irritating, may cause coughing or difficult breatingh
Skin irritation, flush affected areas with water
Eyes irritating to eyes, flush with water
Ingestion irritating by mouth.

3.) INFORMATION ON INGREDIENTS
 
  EINECS PERCENT CAS NO:
232-694-8 100% 9007-13-0
  EINECS PERCENT CAS NO:

4.) FIRST AID MEASURES
 
Inhalation
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical help
Skin Contact
Remove contaminated clothes and shoes. Wash affected area with soap and water. Flush skin with water, seek medical attention if irritation occurs.
Eye Contact
In case of contact, immediately flush eyes with large amounts of water for at least 15 minutes. See medical attention.
Ingestion Contact
If ingested, remove by gastric lavage. Get medical attention immediately.

5.) FIRE FIGHTING MEASURES
 
Extinguishing Media
Dry chemical, sand, water spray, or foam.
Special Fire Fighting Procedures
Move containers if possible. Cool containers with water well after fire is out.
Fire and Explosion Hazzards
Fine dust in air may be ignition source. Can catch fire when overheated.
Hazardous Combustion Products
May release acrid smoke and irritating fumes.
Protective Measure in Fire
Avoid breathing vapors.

6.) ACCIDENTAL RELEASE MEASURES
 
Personal Precaution in Spill
Wear personal protective equipment as described in Section 8.
Environment
Keep unnecessary people away. No flares in hazard area.
Spill Clean Up
Shut off ignition sources. Pick up with clean shovel and place in clean container (dry) and cover. For larger spills, dike ahead and wet down with water.

7.) HANDLING AND STORAGE
 
Usage Precautions
Usage Descriptions
Storage Precautions
Handling Precautions
Store in clean, tightly covered drum. Keep away from combustible material. Keep away from heat. Store in a cool, dry area.

8.) EXPOSURE CONTORLS AND PERSONAL PROTECTION
 
Protective Equipment
Provide general dilution ventilation system.
Process Conditions
Exposure Limits: 5 mg/m3 OSHA TWA (Respirable Dust), 15 mg/m3 OSHA TWA (total dust)
Respirators
Use OSHA-approved dust mask.
Protective Gloves
Wear protective gloves.
Eye Protection
Wear splash-proof, dust-proof safety goggles.
Other Protection
Wear impervious clothing to prevent prolonged skin contact.
Hygienic Work Practices
No eating or smoking in work area. Eye fountain near work area. Good personal hygiene.

9.) PHYSICAL AND CHEMICAL PROPERTIES
 
a) Appearance (physical state, color, etc.)
tan-white powder
b) Odor
mild rosin odor
c) Odor threshold
No data available
d) pH
No data available
e) Melting Point/freezing point
Decomposes
f) Initial boiling Point and boiling range
Decomposes
g) Flash Point
Not applicable
h) Evaporation rate
No data available
i) Flammability (solid,gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure
No data available
l) Vapor density
No data available
m) Relative density
1.13 g/ml @ 25 C
n) Solubility(ies)
Insoluble No data available
o) Partition coefficient: n-octanol/water
No data available
p) Auto-ignition temperature
No data available
q) Decomposition temperature
Not applicable
r) Viscosity
No data available
s) Specific Gravity
No data available

10.) STABILITY AND REACTIVITY
 
Stability
Stable in air-tight containers. May result in spontaneous heating when in contact with air. May be sufficient to ignite material.
Hazardous Decomp Products
Thermal decomposition may release acrid smoke and irritating fumes.
Conditions to Avoid
Strong oxidants

11.) TOXICOLOGICAL INFORMATION
 
Toxic Dose LD 50
Toxicity of calcium resinate has not been qualified.
Toxicological Info
No information found.
Inhalation
May be irritant to mucous membranes.
Skin
May be irritant to skin.
Eyes
May be irritant to eyes.
Medical Symptoms
No information found.

12.) ECOLOGICAL INFORMATION
 
Toxicity
No information found.
Distribution
No information found.
Chemical Fate
No information found.

13.) DISPOSAL CONSIDERATIONS
 
Disposal Methods
Dispose of in a manner that complies with federal, state, and local regulations.
General Cleaning

14.) TRANSPORTATION INFORMATION
 
DOT - GROUND TRANSPORTATION
Proper Shipping Name
Calcium Resinate, Fused
Hazzard Class
4.1
UN Number
UN1314
Packing Group
III
IATA/IMDG REGULATIONS
Proper Shipping Name
Calcium Resinate, Fused
Hazzard Class
4.1
UN Number
UN1314
Packing Group
III
IMDG EMS
F-A,S-I
Shipping Options for this product include
UPS    FedEx    Plane    Truck    Boat    Rail

Transportation Notes NMFC 44515-2 - CL 77.5 HST 3806.90.00.00 UPS - 25 KG (55 LBS) MAX FOR AIR SHIPMENTS


15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient CASNO TSCA EINECS China Japan Austrialia
Calcium Resinate I (Fused) 9007-13-0 No No No No No

Chemical Inventory Status Part 2
Ingredient CASNO Korea DSL NDSL Phil.
Calcium Resinate I (Fused) 9007-13-0 No No No No

Federal, State, International Regulations- Part 1
Ingredient CASNO SARA 302
    RQ TPQ LIST
Calcium Resinate I (Fused) 9007-13-0 No No No
SARA 313
No information found.

Federal, State, International Regulations- Part 2
Ingredient CASNO RCRA 261.33 TSCA 8(d) CERCLA
Calcium Resinate I (Fused) 9007-13-0 No No No

Additional Items
Chemical Weapons Convention Acute TSCA 12(b) CDTA SARA 311/312 Reactivity Chronic
No No No No No No No
Fire Pressure Austrialian HazChem Code Poison Schedule WHMIS
No No No No No

16.) MISC. INFORMATION
 
Information Sources
Revision Comments
Revised November 2012 for GHS Standards. Updated 2-20-15 Revised February 2014 to align with internal document control
Other Information

17.) DISCLAIMER
 
Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this SDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this SDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except that it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.