Barium & Chemicals, Inc.

Safety Data Sheet
Revision: 5
Revision Date: 8/23/2016

 


1.) Identification
 
        Product Name: Calcium Peroxide
        Product Number: CA1500
        Product Formula: CaO2
 
        Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

        Emergency Phone: Chemtrec 800-424-9300
        International: 703-527-3887

2.) HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Oxidizer, Target Organ Effect, Irritant
Target Organs
Skin, Eyes, Respiratory system
GHS Classifications
Oxidizing solids (Category 2)
Skin irritation (Category 2)
Eye irritation (Category 2A)
GHS Label Elements, Including Precautionary Statements
Pictogram
Signal Word     Danger
Hazard Statement(s)
H272 May intensify fire; oxidizer
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
 
Precautionary Statement(s)
P220 Keep/store away from clothing/combustible materials.
P261 Avoid breathing dust/fume/gas/mist/vapor/spray
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 
HMIS Classification
Health Hazard 2
Flammability 0
Physical Hazards 2
Chronic Health Hazard *
 
NFPA Rating
Health Hazard 2
Fire 0
Reactivity Hazard 2
 
Potential Health Effects
Inhalation May be harmful if inhaled. Causes respiratory tract irritation.
Skin May be harmful if absorbed through skin. Causes skin irritation.
Eyes Causes eye irritation.
Ingestion May be harmful if swallowed.

3.) INFORMATION ON INGREDIENTS
 
  EINECS PERCENT CAS NO:
215-139-4 75% 78403-22-2
  EINECS PERCENT CAS NO:

4.) FIRST AID MEASURES
 
Inhalation
Get victim to fresh air, if victim is not breathing initiate artifical respiration and seek medical help immediately.
Skin Contact
Wash with soap and water.
Eye Contact
Flush with water for 15 minutes. Seek medical assistance
Ingestion Contact
DO NOT INDUCE VOMITING. Rinse mouth and dilute by drinking 1-2 glasses of water.

5.) FIRE FIGHTING MEASURES
 
Extinguishing Media
Water.
Special Fire Fighting Procedures
Use flooding quantities of water. Use water spray to keep exposed containers cool.
Fire and Explosion Hazzards
No information found.
Hazardous Combustion Products
Decomposition at high temperatures releases oxygen.
Protective Measure in Fire
No information found.

6.) ACCIDENTAL RELEASE MEASURES
 
Personal Precaution in Spill
Wear personal protective equipment as described in Section 8.
Environment
Avoid runoff into sewers and ditches.
Spill Clean Up
Contain spill, sweep-up, place in disposal container.

7.) HANDLING AND STORAGE
 
Usage Precautions
Usage Descriptions
Storage Precautions
Handling Precautions
Store in a cool, dry place. Avoid incompatible materials.

8.) EXPOSURE CONTORLS AND PERSONAL PROTECTION
 
Protective Equipment
Use adequate ventilation in work area to reduce exposure to eyes.
Process Conditions
No information found.
Respirators
Use NIOSH/NSHA approved respirator.
Protective Gloves
Wear suitable gloves to protect hands from contact.
Eye Protection
Wear suitable protective goggles or glasses to protect eyes from dust.
Other Protection
Wear suitable clothing to protect skin from dust.
Hygienic Work Practices
No information found.

9.) PHYSICAL AND CHEMICAL PROPERTIES
 
a) Appearance (physical state, color, etc.)
White to off-white powder
b) Odor
odorless
c) Odor threshold
No data available
d) pH
No data available
e) Melting Point/freezing point
> 365 C (>689 F)
f) Initial boiling Point and boiling range
No data available
g) Flash Point
Not applicable
h) Evaporation rate
No data available
i) Flammability (solid,gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure
No data available
l) Vapor density
No data available
m) Relative density
No data available
n) Solubility(ies)
No data available No data available
o) Partition coefficient: n-octanol/water
No data available
p) Auto-ignition temperature
No data available
q) Decomposition temperature
No data available
r) Viscosity
No data available
s) Specific Gravity
No data available

10.) STABILITY AND REACTIVITY
 
Stability
Stable under ordinary conditions of use and storage.
Hazardous Decomp Products
Yields oxygen.
Conditions to Avoid
Keep away from reducing agents, heavy metals, combustible materials, mixtures with polysulfide polymers. Strong oxidizing agents, organic materials, powdered metals, water, fluorine, ethanol

11.) TOXICOLOGICAL INFORMATION
 
Toxic Dose LD 50
Oral LD 50 > 5 g / kg rat [FMC 188-1052]
Toxicological Info
Non-given
Inhalation
LC 50: > 17 mg / l (1 hr) rat [FMC ICG/T-79.026]
Skin
non-irritating
Eyes
irritating to unwashed eyes
Medical Symptoms
Not applicable

12.) ECOLOGICAL INFORMATION
 
Toxicity
Non-toxic.
Distribution
No information found.
Chemical Fate
No information found.

13.) DISPOSAL CONSIDERATIONS
 
Disposal Methods
Dispose of in manner that complies with federal, state, and local regulations.
General Cleaning

14.) TRANSPORTATION INFORMATION
 
DOT - GROUND TRANSPORTATION
Proper Shipping Name
OXIDIZING SOLID, NOS (Calcium Peroxide)
Hazzard Class
5.1
UN Number
UN1457
Packing Group
II
IATA/IMDG REGULATIONS
Proper Shipping Name
OXIDIZING SOLID, NOS (Calcium Peroxide)
Hazzard Class
5.1
UN Number
UN1457
Packing Group
II
IMDG EMS
F-G, S-Q
Shipping Options for this product include
UPS    FedEx    Plane    Truck    Boat    Rail

Transportation Notes NMFC 43940-2 CL 85 HST 2917.39.20.00 UPS - NO AIR SHIPMENTS


15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient CASNO TSCA EINECS China Japan Austrialia
Calcium Peroxide 78403-22-2 Yes No No Yes Yes

Chemical Inventory Status Part 2
Ingredient CASNO Korea DSL NDSL Phil.
Calcium Peroxide 78403-22-2 Yes No No Yes

Federal, State, International Regulations- Part 1
Ingredient CASNO SARA 302
    RQ TPQ LIST
Calcium Peroxide 78403-22-2 No No No
SARA 313
No information found.

Federal, State, International Regulations- Part 2
Ingredient CASNO RCRA 261.33 TSCA 8(d) CERCLA
Calcium Peroxide 78403-22-2 No No No

Additional Items
Chemical Weapons Convention Acute TSCA 12(b) CDTA SARA 311/312 Reactivity Chronic
No No No No No No No
Fire Pressure Austrialian HazChem Code Poison Schedule WHMIS
No No No No No

16.) MISC. INFORMATION
 
Information Sources
Revision Comments
Revised November 2012 for GHS Standards. Updated 2-20-15 Revised February 2014 to align with internal document control Updated 8-23-16
Other Information

17.) DISCLAIMER
 
Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this SDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this SDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except that it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.