Barium & Chemicals, Inc.

Safety Data Sheet
Revision: 0
Revision Date: 5/6/2015

 


1.) Identification
 
        Product Name: Anneel-Pak
        Product Number: AP1000
        Product Formula:
 
        Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

        Emergency Phone: Chemtrec 800-424-9300
        International: 703-527-3887

2.) HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Carcinogen
Target Organs
GHS Classifications
Acute toxicity, Dermal (Category 5)
Carcinogenicity (Category 2)
GHS Label Elements, Including Precautionary Statements
Pictogram
Signal Word     Warning
Hazard Statement(s)
H313 May be harmful in contact with skin.
H351 Suspected of causing cancer.
 
Precautionary Statement(s)
P281 Use personal protective equipment as required.
 
HMIS Classification
Health Hazard 0
Flammability 0
Physical Hazards 0
*
 
NFPA Rating
Health Hazard 0
Fire 0
Reactivity Hazard 0
 
Potential Health Effects
Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Ingestion May be harmful if swallowed.

3.) INFORMATION ON INGREDIENTS
 
  EINECS PERCENT CAS NO:
100% 64743-05-1
  EINECS PERCENT CAS NO:

4.) FIRST AID MEASURES
 
Inhalation
Remove to fresh air. If breathing has stopped, administer artificial respiration and supply oxygen. If problem persists, seek medical attention.
Skin Contact
Particles should be periodically washed off of skin with soap and water.
Eye Contact
Immediately flush eyes with plenty of water until irritation subsides. If irritation persists, seek medical attention.
Ingestion Contact
Do not induct vomiting. Immediately give water. Never give anything by mouth to an unconscious person. If symptoms develop, seek medical attention.

5.) FIRE FIGHTING MEASURES
 
Extinguishing Media
Water fog, dry chemical, foam, or carbon dioxide.
Special Fire Fighting Procedures
Most reported coke fires have occurred when produced calcined coke is inadequately cooled and stored in a manner that allows the movement of air through the coke bed. May burn if exposed to temperatures greater than 1290F (700C). Should a fire occur, its locations and extent should be determined as quickly as possible. The best procedure is to dig out and remove the coke in the heated zone. The hot coke should be drenched with water as it is exposed.
Fire and Explosion Hazzards
There is a possibility of a steam explosion when introducing water into confined storage such as a silo. There is no dust explosion hazard from calcined petroleum coke. This product also may burn if exposed to temperatures greater than 700C (1290F).
Hazardous Combustion Products
Products of combustion may contain carbon monoxide, carbon dioxide, and sulfur dioxide.
Protective Measure in Fire
Do not enter permitted confined space or enclosed area without proper PPE.

6.) ACCIDENTAL RELEASE MEASURES
 
Personal Precaution in Spill
Wear PPE as directed in Section 10.
Environment
Provisions should be made to prevent washing, draining, or directing material to storm or sanitary sewers.
Spill Clean Up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

7.) HANDLING AND STORAGE
 
Usage Precautions
Usage Descriptions
Storage Precautions
Handling Precautions
Coke should be well quenched or cooled before it is stored in a pile out of doors or placed in silos or bins. Storage should be arranged to prevent movement of air through coke. Whenever possible, bulk material in silos should be removed and material drenched in an open area.

8.) EXPOSURE CONTORLS AND PERSONAL PROTECTION
 
Protective Equipment
Dust should be controlled at point of operation.
Process Conditions
OSHA: PEL= 15 mg/m3 as total dust; 5 mg/m3 as respirable fraction. ACGIH: PEL= 10 mg/m3 as total dust; 3 mg/m3 as respirable fraction.
Respirators
Select appropriate NIOSH-approved protection where necessary to maintain exposures below the acceptable limits. Proper respiratory selection should be determined by adequately trained personnel and based on the contaminant(s), the degree of potential exposure, and published respirator factors.
Protective Gloves
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Eye Protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU).
Other Protection
The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Hygienic Work Practices
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of work day.

9.) PHYSICAL AND CHEMICAL PROPERTIES
 
a) Appearance (physical state, color, etc.)
dark gray to black solid
b) Odor
No data available
c) Odor threshold
No data available
d) pH
No data available
e) Melting Point/freezing point
No data available.
f) Initial boiling Point and boiling range
No data available
g) Flash Point
No data available
h) Evaporation rate
No data available
i) Flammability (solid,gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure
No data available
l) Vapor density
No data available
m) Relative density
No data available
n) Solubility(ies)
Not soluble in water. No data available
o) Partition coefficient: n-octanol/water
No data available
p) Auto-ignition temperature
No data available
q) Decomposition temperature
No data available
r) Viscosity
No data available
s) Specific Gravity
No data available

10.) STABILITY AND REACTIVITY
 
Stability
Stable.
Hazardous Decomp Products
CO, CO2, SO2
Conditions to Avoid
Strong oxidizing acids, other strong oxidants, extreme heat, and open flames

11.) TOXICOLOGICAL INFORMATION
 
Toxic Dose LD 50
No information found.
Toxicological Info
Petroleum coke was found not to be mutagenic in a rat in vivo Bone Marrow Cytogenic test, a mouse Lymphoma assay, and an Ames Mutagenicity assay.
Inhalation
Petroleum coke was found not to be carcinogenic in monkeys and rats in a two-year inhalation study at concentrations up to 30 mg/m3.
Skin
Petroleum coke was found to be non-carcinogenic in mice in chronic sking painting studies with coke dust.
Eyes
No information found.
Medical Symptoms
Chronic inflammatory changes similar to those produced by non-specific respiratory irritants were observed in some rats at the highest exposure level.

12.) ECOLOGICAL INFORMATION
 
Toxicity
No information found.
Distribution
No information found
Chemical Fate
No information found.

13.) DISPOSAL CONSIDERATIONS
 
Disposal Methods
All Federal, State, and Local regulations regarding health and pollution must be followed for disposal of calcined petroleum coke.
General Cleaning
Product may be picked up by sweeping shoveling or vacuuming, however provisions to prevent wahing, draining, or directing material to strom or sanitary sewers should be taken.

14.) TRANSPORTATION INFORMATION
 
DOT - GROUND TRANSPORTATION
Proper Shipping Name
ORM-C (Anneel-Pak)
Hazzard Class
4.2
UN Number
NA1361
Packing Group
III
IATA/IMDG REGULATIONS
Proper Shipping Name
ORM-C (Anneel-Pak)
Hazzard Class
4.2
UN Number
NA1361
Packing Group
III
IMDG EMS
Not Regulated.
Shipping Options for this product include
FedEx    Truck    Rail

Transportation Notes Regulated by water mode only, when temperatures exceed 130 F, Petroleum Coke, Calcined, not regulated by IMO. Must be loaded in cargo vessels when the temperature exceeds 225 F (46 CFR 148.04-17)


15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient CASNO TSCA EINECS China Japan Austrialia
Anneel-Pak 64743-05-1 No No No No No

Chemical Inventory Status Part 2
Ingredient CASNO Korea DSL NDSL Phil.
Anneel-Pak 64743-05-1 No No No No

Federal, State, International Regulations- Part 1
Ingredient CASNO SARA 302
    RQ TPQ LIST
Anneel-Pak 64743-05-1 No No No
SARA 313

Federal, State, International Regulations- Part 2
Ingredient CASNO RCRA 261.33 TSCA 8(d) CERCLA
Anneel-Pak 64743-05-1 No No No

Additional Items
Chemical Weapons Convention Acute TSCA 12(b) CDTA SARA 311/312 Reactivity Chronic
No No No No No No No
Fire Pressure Austrialian HazChem Code Poison Schedule WHMIS
No No No No No

16.) MISC. INFORMATION
 
Information Sources
Revision Comments
Revised November 2012 for GHS Standards. Updated 2-20-15 Revised February 2014 to align with internal document control.
Other Information

17.) DISCLAIMER
 
Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this SDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this SDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except that it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.