Barium & Chemicals, Inc.

Safety Data Sheet
Revision: 0
Revision Date: 5/6/2015

 


1.) Identification
 
        Product Name: Sodium Oxalate
        Product Number: SO1400
        Product Formula: Na2C2O4
 
        Manufacturer: Barium & Chemicals, Inc.
PO Box 218
515 Kingsdale Road
Steubenville, Ohio 43952-5218

Phone: 740-282-9776
Fax: 740-282-9161
Web: www.bariumchemicals.com

        Emergency Phone: Chemtrec 800-424-9300
        International: 703-527-3887

2.) HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Target organ effect, harmful by ingestion. Harmful by skin absorption
Target Organs
Kidney, nerves, blood eyes
GHS Classifications
Category 4
Category 4
GHS Label Elements, Including Precautionary Statements
Pictogram
Signal Word     Warning
Hazard Statement(s)
H302 / H312 Harmful if swallowed or in contact with skin
 
Precautionary Statement(s)
P264 Wash skin thoroughly after handling
P270 Do not eat, dring or smoke when using this product
P280 Wear protective gloves/protective clothing
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P302 +P352 IF ON SKIN: Wash with plenty of soap and water
P363 Wash contaminated clothing before reuse.
 
HMIS Classification
Health Hazard 1
Flammability 0
Physical Hazards 0
 
NFPA Rating
Health Hazard 1
Fire 0
Reactivity Hazard 0
 
Potential Health Effects
Inhalation May be harmful if inhaled. May cause respiratory tract irritation
Skin Harmful if absorbed through skin. May cause skin irritation
Eyes May cause eye irritation
Ingestion Harmful if swallowed

3.) INFORMATION ON INGREDIENTS
 
  EINECS PERCENT CAS NO:
200-550-3 99-100% 62-76-0
  EINECS PERCENT CAS NO:

4.) FIRST AID MEASURES
 
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin Contact
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Ingestion Contact
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Warning
GHS classification

5.) FIRE FIGHTING MEASURES
 
Extinguishing Media
Use any means suitable for extinguishing surrounding fire. Water spray, Alcohol-resistant foam, dry chemcial or carbon dioxide fire extinguishers
Special Fire Fighting Procedures
Not considered to be a fire hazard.
Fire and Explosion Hazzards
Not considered to be an explosion hazard.
Hazardous Combustion Products
Hazardous decomposition products formed under fire conditions - Carbon oxides and sodium oxides
Protective Measure in Fire
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6.) ACCIDENTAL RELEASE MEASURES
 
Personal Precaution in Spill
Wear appropriate personal protective equipment as specified in Section 8.
Environment
Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Do no let product enter drains
Spill Clean Up
Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.

7.) HANDLING AND STORAGE
 
Usage Precautions
Avoid contact with skin and eyes. Avoid formation of dust and aerosols
Usage Descriptions
Provide adequate exhaust ventilation at places where dust is formed. Normal measures for preventative fire protection
Storage Precautions
Keep containers tightly closed and in a dry well ventilated place. Hygroscopic
Handling Precautions
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8.) EXPOSURE CONTORLS AND PERSONAL PROTECTION
 
Protective Equipment
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Process Conditions
No airborne exposure limits established.
Respirators
For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Protective Gloves
Wear protective gloves.
Eye Protection
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Protection
Wear clean body-covering clothing.
Hygienic Work Practices
No information found.

9.) PHYSICAL AND CHEMICAL PROPERTIES
 
a) Appearance (physical state, color, etc.)
White powder
b) Odor
odorless
c) Odor threshold
No data available
d) pH
No data available
e) Melting Point/freezing point
250 - 270C
f) Initial boiling Point and boiling range
No data available
g) Flash Point
No data available
h) Evaporation rate
No data available
i) Flammability (solid,gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure
No data available
l) Vapor density
No data available
m) Relative density
2.340 g/cm3
n) Solubility(ies)
soluble ca. 13.4 g/l @ 20C (68F)
o) Partition coefficient: n-octanol/water
No data available
p) Auto-ignition temperature
No data available
q) Decomposition temperature
250C (482 F)
r) Viscosity
No data available
s) Specific Gravity
No data available

10.) STABILITY AND REACTIVITY
 
Stability
Stable under ordinary conditions of use and storage.
Hazardous Decomp Products
May produce acrid smoke and irritating fumes when heated to decomposition.
Conditions to Avoid
Heat, incompatibles (Strong oxidizers and strong acids.) Thermal decomposition at 250 C.

11.) TOXICOLOGICAL INFORMATION
 
Toxic Dose LD 50
No LD50/LC50 information found relating to normal routes of occupational exposure.
Toxicological Info
No information found.
Inhalation
No information found.
Skin
No information found.
Eyes
No information found.
Medical Symptoms
No information found.

12.) ECOLOGICAL INFORMATION
 
Toxicity
Toxic to Fish - LC50 630 mg/l - 96 h
Distribution
No information found.
Chemical Fate
No information found.

13.) DISPOSAL CONSIDERATIONS
 
Disposal Methods
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
General Cleaning

14.) TRANSPORTATION INFORMATION
 
DOT - GROUND TRANSPORTATION
Proper Shipping Name
Sodium Oxalate
Hazzard Class

UN Number

Packing Group

IATA/IMDG REGULATIONS
Proper Shipping Name
Sodium Oxalate
Hazzard Class

UN Number

Packing Group

IMDG EMS

Shipping Options for this product include
UPS    FedEx    Plane    Truck    Boat    Transportation Notes NMFC 46460 -- CLASS 70 HST 2917.11.00.00 UPS 25 KG (55 LBS) MAX IN AIR SHIPMENTS


15.) REGULATORY INFORMATION
Chemical Inventory Status Part 1
Ingredient CASNO TSCA EINECS China Japan Austrialia
Sodium Oxalate 62-76-0 Yes Yes No Yes Yes

Chemical Inventory Status Part 2
Ingredient CASNO Korea DSL NDSL Phil.
Sodium Oxalate 62-76-0 Yes Yes No Yes

Federal, State, International Regulations- Part 1
Ingredient CASNO SARA 302
    RQ TPQ LIST
Sodium Oxalate 62-76-0 No No No
SARA 313
No information found.

Federal, State, International Regulations- Part 2
Ingredient CASNO RCRA 261.33 TSCA 8(d) CERCLA
Sodium Oxalate 62-76-0 No No No

Additional Items
Chemical Weapons Convention Acute TSCA 12(b) CDTA SARA 311/312 Reactivity Chronic
No Yes No No No No Yes
Fire Pressure Austrialian HazChem Code Poison Schedule WHMIS
No No No No No

16.) MISC. INFORMATION
 
Information Sources
Revision Comments
Revised November 2012 for GHS Standards. Updated 2-19-2015 Revised February 2014 to align with internal document control
Other Information

17.) DISCLAIMER
 
Barium & Chemicals, Inc. provides this information as it relates only to the specific product designated herein. All information contained in this SDS should be provided to the user's employees and/or customers. The information contained herein relates only to the environmental, health and safety precautions for the product and is not intended to be relied upon as technical specifications for commercial or other purposes. Do not use the ingredient information and/or ingredient percentages in this SDS as product specification. For product specification refer to a Product Specification and/or a Certificate of Analysis provided by or requested from Barium & Chemicals, Inc. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process. This information is intended only as a guide to the appropriate handling of the product by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a a particular purpose. Conditions of use are beyond the control of Barium & Chemicals, Inc. Users are responsible to verify the applicability of this information under their own operating conditions to determine whether the product is suitable for a particular purpose and assume all risks of use, handling and disposal of the product, or from the publication, reliance upon or other use of the information contained herein. This information is furnished without warranty, expressed or implied;except that it is accurate to the best knowledge of Barium & Chemicals, Inc. and is based upon data obtained from the manufacturer and/or recognized technical sources. Barium & Chemicals, Inc. expressively disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product of information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Barium & chemicals, Inc. assumes no responsibility for use, or reliance upon this information. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user.